ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 1 of 6 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME ARMAFLOOR 500 DF BASE COAT - RESIN PRODUCT USE ■ Used according to manufacturer's directions. SUPPLIER Company: Rhino Linings Australasia Pty Ltd Address: 501- 505 Olsen Avenue Molendinar QLD, 4214 Australia Telephone: +61 7 5585 7000 Fax: +61 7 5539 6399 Email: email@example.com Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code. COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
■ Do not breathe gas/fumes/vapour/spray.
skin contact. ■ Cumulative effects may result
■ Wear suitable protective clothing.
following exposure*. ■ Possible respiratory
■ To clean the floor and all objects contaminated by this
■ Take off immediately all contaminated clothing. ■ In case of accident or if you feel unwell IMMEDIATELY contactDoctor or Poisons Information Centre (show label if possible). Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
4, 4' - methylenebis(2- methylcyclohexanamine)
continued. ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 2 of 6 Section 4 - FIRST AID MEASURES SWALLOWED • For advice, contact a Poisons Information Centre or a doctor at once. • Urgent hospital treatment is likely to be needed. • If swallowed do NOT induce vomiting. • If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. EYE ■ If this product comes in contact with the eyes: • Immediately hold eyelids apart and flush the eye continuously with running water. • Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. • Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. • Transport to hospital or doctor without delay. SKIN ■ If skin or hair contact occurs: • Immediately flush body and clothes with large amounts of water, using safety shower if available. • Quickly remove all contaminated clothing, including footwear. • Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. • Transport to hospital, or doctor. INHALED • If fumes or combustion products are inhaled remove from contaminated area. • Lay patient down. Keep warm and rested. • Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. • Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN ■ Treat symptomatically. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA • Foam. • Dry chemical powder. • BCF (where regulations permit). • Carbon dioxide. FIRE FIGHTING • Alert Fire Brigade and tell them location and nature of hazard. • Wear full body protective clothing with breathing apparatus. • Prevent, by any means available, spillage from entering drains or water course. • Use water delivered as a fine spray to control fire and cool adjacent area. FIRE/EXPLOSION HAZARD • Combustible. • Slight fire hazard when exposed to heat or flame. • Heating may cause expansion or decomposition leading to violent rupture of containers. • On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. FIRE INCOMPATIBILITY • Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. HAZCHEM None Personal Protective Equipment Gas tight chemical resistant suit. Limit exposure duration to 1 BA set 30 mins. Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS • Remove all ignition sources. • Clean up all spills immediately. • Avoid breathing vapours and contact with skin and eyes. • Control personal contact by using protective equipment. continued. ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 3 of 6 Section 6 - ACCIDENTAL RELEASE MEASURES MAJOR SPILLS ■ Moderate hazard. • Clear area of personnel and move upwind. • Alert Fire Brigade and tell them location and nature of hazard. • Wear breathing apparatus plus protective gloves. • Prevent, by any means available, spillage from entering drains or water course. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING • DO NOT allow clothing wet with material to stay in contact with skin. • Avoid all personal contact, including inhalation. • Wear protective clothing when risk of exposure occurs. • Use in a well-ventilated area. • Prevent concentration in hollows and sumps. SUITABLE CONTAINER • Metal can or drum • Packaging as recommended by manufacturer. • Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY • Avoid strong acids, acid chlorides, acid anhydrides and chloroformates. • Avoid contact with copper, aluminium and their alloys. • Avoid reaction with oxidising agents. STORAGE REQUIREMENTS • Store in original containers. • Keep containers securely sealed. • No smoking, naked lights or ignition sources. • Store in a cool, dry, well-ventilated area. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS The following materials had no OELs on our records • Latent aliphatic polyamine:
• 4, 4' - methylenebis(2- methylcyclohexanamine):
PERSONAL PROTECTION RESPIRATOR Type AK-P Filter of sufficient capacity EYE • Chemical goggles. • Full face shield may be required for supplementary but never for primary protection of eyes • Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]. HANDS/FEET • Wear chemical protective gloves, eg. PVC. • Wear safety footwear or safety gumboots, eg. Rubber. • When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots. NOTE: • The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to
• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity. continued. ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 4 of 6 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION OTHER • Overalls. • P.V.C. apron. • Barrier cream. • Skin cleansing cream. ENGINEERING CONTROLS ■ General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in special circumstances. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE White viscous liquid with mild, aldehyde odour; does not mix with water. PHYSICAL PROPERTIES Liquid. Does not mix with water. Sinks in water. Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY • Presence of incompatible materials. • Product is considered stable. • Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS
■ May cause SENSITISATION by skin contact.
■ Possible respiratory sensitiser*. ■ Cumulative effects may result following exposure*. ■ * (limited evidence). TOXICITY AND IRRITATION ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczemainvolves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition knownas reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound.
4,4'-METHYLENEBIS(2-METHYLCYCLOHEXANAMINE):LATENT ALIPHATIC POLYAMINE:■ The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling the epidermis. ■ The material may produce respiratory tract irritation. Symptoms of pulmonary irritation may include coughing, wheezing, laryngitis, shortness ofbreath, headache, nausea, and a burning sensation. Unlike most organs, the lung can respond to a chemical insult or a chemical agent, by first removing or neutralising the irritant and then repairingthe damage (inflammation of the lungs may be a consequence).
The repair process (which initially developed to protect mammalian lungs from foreign matter and antigens) may, however, cause further damage to thelungs (fibrosis for example) when activated by hazardous chemicals. ■ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic conditionknown as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. continued. ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 5 of 6 Section 11 - TOXICOLOGICAL INFORMATION
Dermal (rat) LD50: >5080 mg/kg [Manufacturer]■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczemainvolves a cell-mediated (T lymphocytes) immune reaction of the delayed type. The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
Dermal (rabbit) LD50: 200 mg/kg *Dermal (rabbit) LD50: 400 mg/kg *Inhalation (rat) LC50: 0.42 mg/l/4h *Oral (Rat) LD50: 320 mg/kg *Oral (Rat) LD50: 460 mg/kg *■ For 4,4'-methylenebis(2-methylcyclohexanamine) (DMD):Acute toxicity: In humans (epoxy resins production workers) scleroderma-like skin changes have been described revealing
methylcyclohexanamine) as most probable causative agent. In DMD production workers unspecific skin changes, but no scleroderma-like symptoms wereseen. LD50 rat (oral): > 320 < 460 mg/kg bw, symptoms: unspecific;LC50 rat (inhalation, liquid aerosol): 420 mg/m3/4h, symptoms: irritation of the airways;LD50 rabbit (dermal): > 200 < 400 mg/kg bw, symptoms: cyanosis, necrotic changes at the test site. The substance is highly corrosive to skin (full thickness necrosis after 3 minutes of exposure) and may cause severe damage to eyes. The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. * [BASF]
Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Ingredient Section 13 - DISPOSAL CONSIDERATIONS
• Containers may still present a chemical hazard/ danger when empty. • Return to supplier for reuse/ recycling if possible. Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. • Where possible retain label warnings and MSDS and observe all notices pertaining to the product. Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. A Hierarchy of Controls seems to be common - the user should investigate:• Reduction. • DO NOT allow wash water from cleaning or process equipment to enter drains. • It may be necessary to collect all wash water for treatment before disposal. • In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. • Where in doubt contact the responsible authority. • Recycle wherever possible or consult manufacturer for recycling options. • Consult State Land Waste Authority for disposal. • Bury or incinerate residue at an approved site. • Recycle containers if possible, or dispose of in an authorised landfill. continued. ARMAFLOOR 500 DF BASE COAT - RESIN Chemwatch Independent Material Safety Data Sheet Issue Date: 17-Jun-2010 CHEMWATCH 23-3997 C9317TC(vs) Version No:2.0 CD 2010/2 Page 6 of 6 Section 14 - TRANSPORTATION INFORMATION
Labels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only. HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG
Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients Latent aliphatic polyamine (CAS: 54914-37-3) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" diethyl fumarate (CAS: 623-91-6) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" 4,4'-methylenebis(2-methylcyclohexanamine) (CAS: 6864-37-5) is found on the following regulatory lists; "Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)" No data for ArmaFloor 500 DF Base Coat - Resin (CW: 23-3997) Section 16 - OTHER INFORMATION Denmark Advisory list for selfclassification of dangerous substances Substance
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 17-Jun-2010Print Date: 12-Aug-2010
Faith and the Promises of God Esther 4:10-16 HCSB Esther spoke to Hathach and commanded him to tell Mordecai, (11) "All the royal officials and the people of the royal provinces know that one law applies to every man or woman who approaches the king in the inner courtyard and who has not been summoned-- the death penalty . Only if the king extends the golden scepter will that person live
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