MATERIAL SAFETY DATA SHEET
BLEND PM 8020 (9704)
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
3. HAZARDS IDENTIFICATION
Harmful if inhaled, absorbed through skin, or swallowed. Causes severe eye irritation. Vapours are irritating to eyes and respiratory tract. High vapour concentrations may cause drowsiness. See "Other Health Effects" Section. Flammable liquid and vapour. May cause flash fire or explosion. Can decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged exposure to heat.
Product is irritating to the nose, throat and respiratory tract. Contact with mist or spray may cause irritation of mucous membranes, coughing and difficulty in breathing. See "Other Health Effects" Section.
Prolonged and repeated contact may lead to dermatitis. Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as under rings or watch bands). May cause defatting, drying and cracking of the skin.
May be absorbed through intact skin.
Splashes to the eye may cause severe irritation, redness and pain. Vapours from this product are irritating to the eyes.
This product causes irritation, a burning sensation of the mouth and throat and abdominal pain.
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following any exposure is essential.
May cause central nervous system (CNS) depression, liver damage or kidney damage. CNS depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination. Severe overexposures may lead to coma and possible death due to respiratory failure. Liver damage is characterized by the loss of appetite, jaundice (yellowish skin colour), and occasional pain in the upper left-hand side of the abdomen. Signs and symptoms of kidney damage generally progress from oliguria, to blood in the urine, to total renal failure.
4. FIRST AID MEASURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention IMMEDIATELY.
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. Take care not to rinse contaminated water into the unaffected eye or onto the face. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. IMMEDIATELY contact local Poison Control Centre. Vomiting should only be induced under the direction of a physician or a poison control centre. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim to an emergency facility.
This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed.
Medical conditions that may be aggravated by exposure to this product include neurological and cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney disorders.
5. FIRE-FIGHTING MEASURES
Flammability Limits in Air (%):
Thermal decomposition products are toxic and may include oxides of carbon and irritating gases.
Vapours from this product are heavier than air, and may "travel" to a source of ignition (eg. pilot lights,
heaters, electric motors) some distance away, and then "flash back" to the point of product discharge causing an explosion and fire. Closed containers exposed to heat may explode. Spilled material may cause floors and contact surfaces to become slippery.
Sensitivity to Mechanical Impact: Not expected to be sensitive to mechanical impact.
Expected to be sensitive to static discharge when vapours are present between the lower and upper explosive limits.
Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the form of a fog. This material may produce a floating fire hazard in extreme fire conditions.
Use water spray to cool fire-exposed containers or structures. Use water spray to disperse vapours; re-ignition is possible. Isolate materials that are not involved in the fire and protect personnel. Cool containers with flooding quantities of water until well after the fire is out.
Use self-contained breathing apparatus and protective clothing.
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Wear protective clothing. Do not use combustible materials such as sawdust as an absorbent. Eliminate all sources of ignition. Collect product for recovery or disposal. For release to land, or storm water runoff, contain discharge by constructing dykes or applying inert absorbent; for release to water, utilize damming and/or water diversion to minimize the spread of contamination. Ventilate enclosed spaces. Notify applicable government authority if release is reportable or could adversely affect the environment.
7. HANDLING AND STORAGE
Ground and bond equipment and containers to prevent a static charge buildup. Use spark-resistant tools and avoid "splash-filling" of containers. Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be under internal pressure. These should be cooled and carefully vented before opening. A face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve pressure. Enforce NO SMOKING rules in area of use.
See Section 8, "Engineering Controls".
Use only with adequate ventilation and avoid breathing vapours or mists. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-use. Do not use cutting or welding torches on empty drums that contained this material/product. Store wiping rags and similar material in metal cans with tight fitting lids.
Ventilation should be explosion proof.
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed. Do not expose sealed containers to temperatures above 40° C. Protect from direct sunlight. Protect against physical damage.
Special Materials to be Used for Confirm suitability of any material before using. Attacks some types of rubber, plastics and coatings.
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.
Local exhaust ventilation required. Ventilation should be explosion proof. Make up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense vapours may collect.
For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed. It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision and maintenance of SCBA, and emergency rescue. Use the "buddy" system. The second person should be in view and trained and equipped to execute a rescue. (4)
Safety glasses with side shields. Use full face-shield or chemical safety goggles when there is potential for contact. Contact lenses should not be worn when working with this material.
Gloves and protective clothing made from butyl rubber, polyvinyl alcohol (PVA) or teflon should be impervious under conditions of use. Discard contaminated gloves. Prior to use, user should confirm impermeability.
No specific guidelines available. Do not use compressed oxygen in hydrocarbon atmospheres. A NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for concentrations up to 1 000 ppm organic vapours. An air-supplied respirator if concentrations are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If the seal is no longer good, you may need a new respirator. (4)
Ethyl Acetate: Immediately Dangerous to Life and Health (IDLH) value: 2 000 ppm. (4) The purpose of establishing an IDLH value is to ensure that the worker can escape from a given contaminated environment in the event of failure of the most protective respiratory equipment. In the event of failure of respiratory protective equipment, every effort should be made to exit immediately. (4)
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical
handling area. Take all precautions to avoid personal contact. Clothing and footwear that is fire retardant and dissipates static electrical charges should be worn when handling flammable materials. Natural fibers (cotton, wool, leather and linen) should be selected in favour of synthetic materials (rayon, nylon and polyester).
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
10. STABILITY AND REACTIVITY
High temperatures, sparks, open flames and all other sources of ignition. Protect from direct sunlight. Moisture.
Strong oxidizers. Lewis or mineral acids. Peroxides. Strong bases. Metal hydroxides. Sodium Hydroxide. Amines. Contact of solid Potassium tert-Butoxide with Ethyl Acetate vapour causes ignition in two minutes. Violent explosion can occur between Ethyl Acetate and Lithium Aluminum Hydride. (4) Attacks some types of rubber, plastics and coatings.
Propylene Glycol Monomethyl Ether Acetate: Oxygen exposure may lead to the formation of explosive peroxides.
Thermal decomposition products are toxic and may include oxides of carbon and irritating gases.
11. TOXICOLOGICAL INFORMATION
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP. See "Other Studies Relevant to Material".
No adverse reproductive effects are anticipated.
No adverse mutagenic effects are anticipated.
No adverse teratogenic effects are anticipated.
The combination of ethyl acetate and formaldehyde was more acutely toxic to rats than predicted from the toxicities of the individual chemicals. (4)
Alcohols/Glycols: Alcohols may interact synergistically with chlorinated solvents (example - carbon tetrachloride, chloroform, bromotrichloromethane), dithiocarbamates (example - disulfiram), dimethylnitrosamine and thioacetamide. (4)
Workers exposed regularly to 375 to 1,500 ppm for several months experienced no adverse effects.
Exposure to 400 ppm for 3 to 5 minutes caused irritation to the nose and throat in humans. Symptoms such as tension, tiredness, complaints and annoyance have also been reported during 4 or 8 hour exposures to 400 ppm. Ethyl acetate was not irritating to the skin in tests using human volunteers and animals. (4)
The vapour and liquid can be irritating. The vapour has produced eye irritation in humans at 400 ppm. Animal studies indicate that one drop caused redness and moderate swelling of the eye lasting for 1 to 2 days. Application of 2 drops caused immediate irregularity of the outer layer of the cornea. (4)
Ethyl acetate was not mutagenic in an in vivo study with Chinese hamsters. (4)
Animal studies have shown that the chemically-similar Propylene Glycol Monomethyl Ether (PGME) has no teratogenic or embryotoxic effects. (4)
Propylene Glycol Monomethyl Ether Acetate (PGMEA) is rapidly metabolized to PGME and acetic acid. Propylene Glycol Monomethyl Ether Acetate is not expected to produce chronic effects based on its similarity and metabolism to the chemically-similar PGME. (4)
PGMEA was somewhat painful and irritating to the eyes. (4)
12. ECOLOGICAL INFORMATION
Low acute toxicity to aquatic organisms.
Can be dangerous if allowed to enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers.
13. DISPOSAL CONSIDERATIONS
Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the product may be required by the user at the time of disposal since the product uses, transformations, mixtures and processes may influence waste classification.
See "Waste Disposal Methods".
Empty containers retain product residue (liquid and/or vapour) and can be dangerous. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Do not dispose of package until thoroughly washed out.
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
FLAMMABLE LIQUID, N.O.S. (Ethyl Acetate), Class 3, UN1993, PG II.
Label(s): Flammable Liquids. Placard: Flammable Liquids.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
FLAMMABLE LIQUID, N.O.S. (Ethyl Acetate), Class 3, UN1993, PG II.
Label(s): Flammable Liquid. Placard: Flammable Liquid.
15. REGULATORY INFORMATION
This material is included on the DSL under the CEPA.
Controlled Products Regulations Classification (WHMIS):
This material is included on the TSCA Inventory.
OSHA HCS (29CFR 1910.1200): Flammable Liquid. Eye Irritant.
16. OTHER INFORMATION
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS database.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, New York, 1981.
Supplier's Material Safety Data Sheet(s).
CHEMINFO chemical profile, Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
Guide to Occupational Exposure Values, 2011, American Conference of Governmental Industrial Hygienists, Cincinnati, 2011.
Regulatory Affairs Group, Brenntag Canada Inc.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical Association, Ottawa, 1981.
NFPA 325M Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids, 1994 Edition, Quincy, MA, 1994.
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained herein. This Material Safety Data Sheet is valid for three years.
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1 Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9 Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2 Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6 Phone: (416) 259-8231 Facsimile: (416) 259-5333
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8 Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7 Phone: (902) 468-9690 Facsimile: (902) 468-3085____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
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